OCR A-level Organic Chemistry Reactions 0.0 / 5 ? ChemistryOrganic SynthesisA2/A-levelOCR Created by: JameslightningfistswheelerCreated on: 02-05-19 17:32 Benzene --> Chlorobenzene Halogenation, Halogen Carrier catalyst 1 of 41 Benzene --> Nitrobenzene conc. HNO3, Reflux, 50 degrees, H2SO4 catalyst 2 of 41 Nitrobenzene --> Phenylamine Reduction, Tin, conc. HCl, Reflux , 100 degrees 3 of 41 Benzene --> Alkylbenzene Alkylation, haloalkane, halogen carrier catalyst 4 of 41 Benzene --> Benzaldehyde Acyl Chloride, Reflux at 60 degrees for 30 mins, halogen carrier catalyst 5 of 41 Benzene --> Phenylketone Acyl Chloride (c=o not on the end), reflux, halogen carrier catalyst 6 of 41 Phenol --> 2,4,6-Tribromophenol Br2, RTP= triple sub 7 of 41 Phenol --> 2- Nitrophenol + 4-Nitrophenol HNO3, (dilute= 1 sub, conc.= 3sub) 8 of 41 Alkane --> Haloalkane Radical Substitution, Cl2/Br2, UV light or 300 deg. 9 of 41 Alkane --> Alkene Cracking 10 of 41 Alkene --> Alkane Hydrogenation, H2, Ni catalyst, 150 deg. 11 of 41 Alkene --> Haloalkane Halogenation, halogen/ halogen halide, RTP 12 of 41 Alkene --> Alcohol Hydration, H2O, 300 deg., H3PO4 catalyst 13 of 41 Alcohol --> Alkene Dehydration, 170 deg., H2SO4 catalyst 14 of 41 Primary Alcohol --> Aldehyde Oxidation, K2Cr2O7/H2SO4, distillation 15 of 41 Aldehyde --> Primary Alcohol Reduction, NaBH4 16 of 41 Primary Alcohol --> Carboxylic Acid Oxidation, K2CR2O7/H2SO4, reflux 17 of 41 Secondary Alcohol --> Ketone Oxidation, K2CR2O7/H2SO4, reflux 18 of 41 Ketone --> Secondary Alcohol Reduction, NaBH4 19 of 41 Alcohol --> Ester Carboxylic Acid, reflux, conc. H2SO4 catalyst 20 of 41 Alcohol--> Haloalkane Hydrogen Halide, H2SO4 catalyst 21 of 41 Haloalkane --> Alcohol Hydrolysis, NaOH, Reflux 22 of 41 Carboxylic Acid --> Acyl Chloride SOCl2, RTP 23 of 41 Acyl Chloride --> Carboxylic Acid Hydrolysis, H2O 24 of 41 Acyl Chloride --> Amide NH3 25 of 41 Amide --> Polyamide Condensation Polymerisation 26 of 41 Carboxylic Acid --> Ester Alcohol, reflux, conc. H2SO4 catalyst 27 of 41 Acyl Chloride --> Ester Alcohol, RTP (higher yield as it isn't reversible) 28 of 41 Ester --> Carbocylic Acid + Alcohol Acid Hydrolysis, dilute HCl Catalyst, reflux 29 of 41 Ester --> Carboxylate salt + Alcohol Alkali Hydrolysis, Hot NaOH, reflux (carboxylate salt is a carboxylic acid with the H of the -OH replaced by a metal or ammonium ion) 30 of 41 Ester --> Polyester Condensation Polymerisation 31 of 41 Polyester --> Carboxylic Acid + Alcohol Acid Hydrolysis, dilute HCl catalyst, reflux 32 of 41 Polyester --> Carboxylate Salt + Alcohol Alkali Hydrolysis, Hot NaOH, reflux 33 of 41 Haloalkane --> Amine NH3, Ethanol, heat 34 of 41 Haloalkane --> Nitrile KCN, Ethanol, reflux 35 of 41 Nitrile --> Amine Reduction, H2, Ni catalyst, 150 deg. OR LiAlH4 Reducing Agent 36 of 41 Amine --> Polyamide Condensation Polymerisation, Dicarboxylic Acid 37 of 41 Polyamide --> Dicarboxylic Acid + Diammonium Salt Acid Hydrolysis, HCl, reflux (Acid hydrolysis is slower than alkali hydrolysis of polyamides 38 of 41 Polyamide --> Dicarboxylate Salt + Diamine Alkali Hydrolysis, Hot NaOH, reflux 39 of 41 Aldehyde --> Hydroxynitrile NaCN, acidic conditions 40 of 41 Nitrile --> Carboxylic Acid dilute HCl catalyst, reflux, acid hydrolysis 41 of 41
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