Synthesis
C2
- Created by: Belinda
- Created on: 30-05-11 11:28
Balancing Equations & Carbon Compounds
Chemical Reactions = mass of reactant to the mass of the product
must be the same number of atoms on both sides of the equation
Carbon is an element found in group four (four electrons in its outer shell)
Has the ability to form four bonds with other atoms
Bonds on the carbon atoms remain free to join with other atoms to form carbon compounds
Carbon compounds are organic compounds = basis of life
E.g proteins, amino acids, carbohydrates, fats, fossil fuels, plastics these are called organic chemistry
Alkanes & Alkenes
Alkanes (saturated hydrocarbons) = a hyrdrocarbon (Compound containing hydrogen and carbvon) They are join by single covalent carbon-carbon bonds.
A covalent bond is a strong bond when electrons are shared between non-metal atoms.
The maximum number of atoms are used so the hydrocarbon is saturated.
This is called an Alkane
Ethane Propane and Butane (3 simpliest alkanes)
Alkenes (unsaturated hydrocarbons) are joined by double covalent carbon-carbon bonds.
They are not bonded to the maximum number of atoms so are unsaturated hydrocarbons.
Ethen and propene (Simpliest alkenes)
'ene' (colourless) + Bromine water (yellow brown) > Colourless solution
'ane' (colourless) + Bromine water (yellow brown) > Yellow brown solution
Cracking
= Breaking down long chain hydrocarbons
Short chain hydrocarbons release more energy when burned
Long chain hydrocarbons is heated until it vaporises
Vapour is passed over a heated catalyst, thermal decomposition Reaction takes place
When alkanes are cracked alkanes and alkenes are formed
Monomers to polymers & Properties of Polymers
Polymers are long chain molecules formed from unsaturated monomers (Monomer = short chain hydrocarbon)
Monomers join polymers through condensatiuon reactions, these sometimes make plastics
Alkenes are unsaturated so are good at joining together without producing another substance (addition polymerisation)
Properties of polymers:
Good strength and elasticity, Don't corrode, Good electrical and thermal insulators, Low densities, Colourful, Easily moulded
Polymers can be divided into:
Thermo plastics, thermosets
Thermo plastics = easily softened and remoulded have weak inter molecular forces, not very rigid
Thermosets = can be softened, can't be resoftened and reshaped after first time heating
Properties of plastics & Disposing plastics
Chemicals can be addded during manufacturing:
Plasticisers - make thermo plastics more flexible
UV and thermal stabilisers - prolong a plastics life
Cross linking agents encourage molecules to cross link, give more stable form of plastic
Disposing plastics is harmful to the environment these include:
Burning - air pollution, greenhouse affect, toxic fumes
Landfill sites - Non bio-degradable, waste builds up
Product Development & Drug synthesis
Product development atom economy
Synthesis methods = knowledge of existing molecules ot predict new reactions
Computer modeling is used to predict shape, structure, properties and how toxic the substance will be by comparing to oter equations.
Any reaction with acid and a base always has the products salt and water
The production process (synthesis) Must produce the desired product in a reasonable quantity quickly and efficently
Scientists make sure processes they use give high atom economy for sustainable development as they provent waste
Not all reactions give a high yeaild or are efficent
Drug synthesis = Development of new medication
Before it was expensive and took many years, now computer stimulation technology makes the process more efficent
1. Tested on humans 2. tested on group of volunteers 3. toxicological study done on compound before compound
Relative formula mass & Empirical formula
Relative formula mass = some of relative atomic mass of all its elements added together. You need to know formula of the compound and relative atomic mass of all atoms involved.
Empirical formula = always divide the data given by the relative atomic mass of the element then simplify ratio for the simpliest formula
To work out how much of a substance is used up or produced in a chemical reaction you have to write the equation, work out relatrive formula mass of each substance, check the totale mass of rectants = total mass of products then you need the ratio mass of first substance.
Atom economy & Yeilds
chemical reactions produce more than one product but not all are useful
starting material (reactants) are converted into useful products most of the time
atom economy is a measure of the amounts of reactants that end up as useful products
Atom economy = (mass of atoms in useful product divided by total mass of atoms of product) x 100%
expected yeild = amount of product expected from a reaction (based on amount of reactants)
2 types of yeilds in a reaction: Theoretical yeild - calculated from masses of atom
Actual yeild - actual mass obtained from the reaction
Percentage yeild = (actual yeild / maximum theoretical yeild) x 100%
Atom economy & Yeilds
chemical reactions produce more than one product but not all are useful
starting material (reactants) are converted into useful products most of the time
atom economy is a measure of the amounts of reactants that end up as useful products
Atom economy = (mass of atoms in useful product divided by total mass of atoms of product) x 100%
expected yeild = amount of product expected from a reaction (based on amount of reactants)
2 types of yeilds in a reaction: Theoretical yeild - calculated from masses of atom
Actual yeild - actual mass obtained from the reaction
Percentage yeild = (actual yeild / maximum theoretical yeild) x 100%
Glossary
Mono unsaturated - an organic compound that only contains one double covalent carbon-carbon bond
Poly unsaturated - an organic compound with more than one double covalent carbon-carbon bond
Comments
No comments have yet been made