Chemistry
GCSE AQA Additional Chemistry
- Created by: Rosalie Moloney
- Created on: 21-05-12 18:14
Ionic
The losing or gaining of electrons.
Ionic compounds are made up of giant ionic lattices, the ions are tightly packed and have strong electrostatic forces of attraction.
Their properties are HIGH melting and boiling point, dissolve easily in water and carry electric current.
Covalent
The sharing of electrons so both atoms have a full outer shell
Simple molecular substances. Atoms form strong covalent bonds to form small molecules that have weak forces of attraction.
These forces are broken easily when boiled or melted (low boiling and melting point), they dont conduct electricity because theres no ions and charge
GIANT covalent structures similar to lattices but have no ions/charge. Strong covalent bonds
e.g;
diamond- strong, hard, rigid, 4 bonds
silicon dioxide- makes sand
graphite- soft and slippery, 3 bonds, weak intermolecular forces between layers, layers slide over eachother, can be rubbed off (pencil)
Metallic Structure
Metalic bonds involve free ions, made up of strong electrostatic forces of attraction between metal ions (+) and electrons (-).
Metals are good conductors of heat and electricity
Alloys are stronger than pure metals as they're a mixture of metals
Smart Materials
Behave in certain ways depending on condition
e.g; Nitinol- Flexible, bend it too far and it stay bent but when heated turns back to remembered shape
...Used for braces and glass frames
NANOPARTICLES (tiny particles containing a few 100 atoms)
- Include fullerenes (carbon molecules) which form to make nanotubes
USES OF NANOSCIENCE: Catalysts, cosmetics, circuits, lube for artificial joints, sensors, strong light building material
Polymers
Thermosoftening plastics - Weak intermolecular forces, when heated are remouldable (chains free to slide over eachother)
Thermosetting plastics - Strong intermolecular forces, chains tightly packed. Doesn't soften when heated
LD POLYETHENE- High temp and pressure, used for plastic bags
HD POLYETHENE - Low temp and pressure, used for tanks
Equations
RFM = RAM added together
RAM = biggest number on element
MOLES are the relative formula mass in grams
Moles = Mass/RFM
MASS OF A COMPOUND
RAM X NO OF ATOMS
---------------------------- X 100
RFM
EMPIRICAL FORMULA
find % of elements then divide that by their RAM then find the ratio
Reactions
PRECIPITATION - When products cloud the solution, observe the solution and see how long marks take to dissapear, faster it dissapears the faster the reaction
CHANGE IN MASS - gas released in a reaction reduces the mass, quicker mass drops, the faster the reaction
VOLUME OF GAS GIVEN OFF - Syringe measure this, more gas given off, the faster the reaction, syringe is to nearest MM so it's accurate
Rate of reaction experiments
HYDROCHLORIC ACID AND MARBLE CHIPS REACTION
Gas given out is measured with syringe
Plot in a table
Repeat experiment with crushed marble, then marble powder
Marble powder, faster reaction (bigger surface area, frequent collisions)
Marble chips, slower reaction (smaller surface area)
MAGNESIUM METAL AND HYDROCHLORIC ACID REACTION
Hydrogen gas is given off, good for measuring effects of high concentration
SODIUM THIOSULFATE + HCL --> CLOUDY PRECIPITATE
Both chemicals clear solution, react to form yellow precipitate of sulfur
DECOMPOSITION OF HYDROGEN PEROXIDE
2 h2 o2 <----> 2 h20 + o2
Slow reaction but manganese oxide catalyses reaction
Collision Theory
High temp, concentration and large surface area = more collisions & faster reaction
Reaction only happens with enough energy, minimum energy is activation energy.
CATALYST - Speed up reaction without being used up or changed
+ Reduce need for high temps in reaction (less money)
Increases reaction rate, saving money
- have to buy many cause each catalyst is specific to reaction
expensive
can stop working
Exothermic and endothermic
Exothermic - energy exits reaction, transferring energy and heating up surroundings
e.g; hand warmers and self heating cans
Endothermic -energy enters reaction taking energy from surrounds and temp of them falls
e.g; thermal decomposition and sports injury packs
Acids and alkalis
Below PH7 = acid
Above PH7 = alkakli
Base is a substance with a bigger ph than 7, alkali is a base disolved in water
H+ = Acid OH- = Alkali
Acid + Base = Salt + Water (Neutralisation)
Acid + Metal = Salt + Hydrogen
Acid + Metal (hydr)oxide = Salt + Water
Making Salts
Pick the right acid + metal (base, oxide or hydroxide).
This will make the solid dissolve in the acid
Acid is neutralised when solid sinks to bottom of the flask
Filter the metal out to get salt, get purer salt by evaporating water then leave rest to evaporate slowly CRYSTALLISATION
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