CH2 - Hydrocarbons
- Created by: zopetre_
- Created on: 02-06-17 10:53
Describe fossil fuels
They are drived from organisms that lived long ago
Include natural gas, petroleum and coal
Much of the worlds industrial and domestic energy needs are met by using them
What are the advantages of fossil fuels?
They are available in a variety of forms, so the type of fuel can be matched with its use
They are all available at all times
What are the disadvantages of fossil fuels?
They are non-renewable due to the fact that they are used up quicker than they are made
Combusion of them produces carbon dioxide, a greenhouse gas that absorbed infrared radiation and emits it in different directions
Acid rain as they many contain sulfur and on combustion this produces sulfur dioxide which reacts with water to make sulfuric(IV) acid which is oxidised to make sulfuric(VI) acid. Causes serious damage to buildings and health problems
Carbon monoxide formation
Describe the homologous series of alkanes
The general formula of them is CnH2N+2
Each member of series differs from neighbour by CH2
They have similar chemical reactions as they're saturated
Physical properties may vary as molecular mass increases
What do alkanes burn by?
They burn by reaction with oxygen, exothermic so they're used as fuels
Sufficient oxygen - complete combustion occurs, produces CO2 and H2O
Insufficient oxygen - incomplete combustion occurs, produces CO and H2O
Describe halogenation
It is the reaction between an organic compound and any halogen, also known as free radical substitution
1) Initiation: UV light breaks bond between molecules and homolytic bond fission occurs to produce a radial
2) Propagation: Radical acts as a reactant, forming a radical as a product by a chain reaction
3) Termination: propagation steps continue until two radicals meet
Describe the structure of alkenes
Homologous series of unsaturated hydrocarbons
They contain a double bond with the general formula CnH2n
They are formed when petrouleum is cracked, generally used as fuels
They are much more reactive alkanes
What do p orbitals do?
They overlap sideways to produec a π bond, an area of high electron density
Describe electrophilic addition reactions
Alkenes have a pair of electrons in a π orbital, they are susceptible to attack by an electrophile (species that can accept a lone pair of electrons)
It involves heterolytic bond fission, leaving to an addition reaction
Mechanism uses curly arrows to show movement of a pair of electrons
Describe the use of electrophilic addition with br
Used as a test for an alkene
Bromine is brown and presence of an alkene is shown by decolorisation of bromine water
Describe the use of electrophilic addition with hy
Hydrogenation
Catalysed by transition metals including platinum, palladium and nickel
Important as liquid vegetable oils can be made saturated by adding hydrogen to harden them to make solid edible fats
What is a carbocation?
A carbocation is a carbon-containing positively charged ion
What is polymerisation?
The joining of a very large number of monomer molecules to make a large polymer molecule
What do alkenes and substituted alkenes undergo?
Addition polymerisation, the double bond is used to join the molecules, polymer doesn't contain a double bond but name is formed by adding poly to name of monomer so it involves ene
What is a repeat unit?
The section of the polymer that is repeated to make the whole structure
What does poly(propene) do?
It is rigid and is used in food containers and general kitchen equipment
What does poly(chloroethene) do?
It can be used in water pipes, in waterproof clothing or as the insulating covering for electrical cable
What does poly(phelyethene) do?
It is hard and is used in many household items needing strength and rigidity
It can be made into an insulator and packing material by creating holes in the structure
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